HomePage >> Journals >> Research of Materials Science

Research of Materials Science

Research of Materials Science is an international comprehensive professional academic journal of Ivy Publisher, concerning the development of materials science theory and technology application, on the combination of materials science theory and modern industrial technology. The main focus of the journal is the academic papers and comments of latest materials science theory research improvement in the fields of nature science, engineering technol... [More] Research of Materials Science is an international comprehensive professional academic journal of Ivy Publisher, concerning the development of materials science theory and technology application, on the combination of materials science theory and modern industrial technology. The main focus of the journal is the academic papers and comments of latest materials science theory research improvement in the fields of nature science, engineering technology, economy and science, report of latest research result, aiming at providing a good communication platform to transfer, share and discuss the theoretical and technical development of materials science theory for professionals, scholars and researchers in this field, reflecting the academic front level, promote academic change and foster the rapid expansion of materials science theory and technology research.

The journal receives manuscripts written in Chinese or English. As for Chinese papers, the following items in English are indispensible parts of the paper: paper title, author(s), author(s)'affiliation(s), abstract and keywords. If this is the first time you contribute an article to the journal, please format your manuscript as per the sample paper and then submit it into the online submission system. Accepted papers will immediately appear online followed by printed hard copies by Ivy Publisher globally. Therefore, the contributions should not be related to secret. The author takes sole responsibility for his views.

ISSN Print:2327-0470

ISSN Online:2327-0489


Website: http://www.ivypub.org/rms/


Paper Infomation

Research advances in three dimensional graphene/ transition metal oxide composite in supercapacitors

Full Text(PDF, 2274KB)

Author: jianming lv, ruiguang xing, bangwen zhang

Abstract: As an intermediate energy storage devices between dielectric capacitors and batteries , supercapacitors have attracted intense attention mainly due to their unique properties such as high output power, long cycling stability, and fast charge/discharge capability. Three dimensional graphene (3DGN) are currently pursued as supercapacitor electrodes because it can provide short diffusion pathways for electrolyte ions and fast transport channels for electrons, and act as an ideal scaffold for forming transition metal oxide to obtain a synergistic effect. This review first outlines the different synthetic methods with respect to 3DGN, then focus on the 3DGN supported transition metal oxide composites, their synthetic routines, structure features and electrochemical properties. Finally, the challenges and future prospects of this kind of composite in supercapacitor applications are presented in the end of the review.

Keywords: Supercapacitors, three dimesional graphene, Transition metal oxide


[1] Lee Jeong-woo, Hall Anthony S. Hall, Kim Jong-duk, et al. A facile and template-free hydrothermal synthesis of Mn3O4 nanorods on graphene sheets for supercapacitor electrodes with long cycle stability[J]. Chemistry of Materials, 2012, 43(24): 1158-1164.

[2] Yu Gui-hua, Hu Lang-bing, Liu Nian, et al. Enhancing the supercapacitor performance of graphene/MnO2 nanostructured electrodes by conductive wrapping[J]. Nano Letters, 2011, 11(10): 4438-4442.

[3] Yang Lei, Cheng Suang, Ding Yomg, et al. Hierarchical network architectures of carbon fiber paper supported cobalt oxide nanonet for high-capacity pseudocapacitors[J]. Nano Letters, 2012, 12(1): 321-325.

[4] Yuan Chang-zhou, Yang Long, Hou Lin-rui. Growth of ultrathin mesoporous Co3O4 nanosheet arrays on Ni foam for high-performance electrochemical capacitors[J]. Energy & Environmental Science, 2012, 5(7): 7883-7887.

[5] Huang Liang, Chen Dong-chang , DingYong , et al. Nickel-cobalt hydroxide nanosheets coated on NiCo2O4 nanowires grown on carbon fiber paper for high-performance pseudocapacitors[J]. Nano Letters, 2013, 13(7): 3135-3139.

[6] Hu Chi-Chang, Chang Kuo-Hsin, Lin Ming-champ, et al. Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors[J]. Nano Letters, 2006, 6(12): 2690-2695.

[7] Martti Kaempgen, Chandace K. Chan, J. Ma, et al. Printable thin film supercapacitors using single-walled carbon nanotubes[J]. Nano Letters, 2009, 9(5):1872-1876.

[8] Xiao Wei, Xia Hui, Jerry Y. H. Fuh, et al. Growth of single-crystal α-MnO2 nanotubes prepared by a hydrothermal route and their electrochemical properties[J]. Journal of Power Sources, 2009, 193(2): 935-938.

[9] Lu Xi-hong, Zheng De-Zhu, Zhai-Teng, et al. Facile synthesis of large-area manganese oxide nanorod arrays as a high-performance electrochemical supercapacitor[J]. Energy & Environmental Science, 2011, 4(8): 2915-2921.

[10] Zhang G Q. Single-crystalline NiCo2O4 nanoneedle arrays grown on conductive substrates as binder-free electrodes for high-performance supercapacitors[J]. Energy & Environmental Science, 2012, 5(11): 9453-9456.

[11] Zhang Gen-qiang, Lou Xiong-wen. General solution growth of mesoporous NiCo2O4 nanosheets on various conductive substrates as high-performance electrodes for supercapacitors[J]. Advanced Materials, 2013, 25(7): 976-979.

[12] Zhao Xin, Tian Hui, Zhu Ming-yao, et al. Carbon nanosheets as the electrode material in supercapacitors[J]. Journal of Power Sources, 2009, 194(2): 1208-1212.

[13] Fan Zhuang-jun, Yan Jun, Zhi Lin-jie, et al. A three-dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors[J]. Advanced Materials, 2010, 22(33): 3723-3728.

[14] Wu Zhong-Shuai, Wang Da-Wei, Ren Wen-cai, et al. Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors[J]. Advanced Functional Materials, 2010, 20(20): 3595-3602.

[15] Zhang Wen-hui, Sun Youyi, Liu Tantan, et al. Preparation of graphene foam with high performance by modified self-assembly method[J]. Applied Physics A, 2016, 122(3): 1-9.

[16] Wang Huan-wen, Yi Huan, Chen xiao. One-step strategy to three-dimensional graphene/VO2 nanobelt composite hydrogels for high performance supercapacitors[J]. Journal of Materials Chemistry A, 2013, 2:1165-1173.

[17] Wu Zhong-shuai, Andreas Winter, Chen Long, et al. Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors[J]. Advanced Materials, 2012, 24(37): 5130-5135.

[18] Xu Yuxi , Sheng Kaixuan , Li Chun, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. Acs Nano, 2010, 4(7): 4324-4330.

[19] M. J. Fernández-merino, L. Guardia, J. I. Paredes, et al. Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions[J]. Journal of Physical Chemistry C, 2010, 114(14): 6426-6432.

[20] Chen Ping, Yang Jing-jing, Li Shuang-shuang, et al. Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor[J]. Nano Energy, 2013, 2(2): 249-256.

[21] Zhao Jin-ping, Ren Wen-cai, Cheng Hui-ming. Graphene sponge for efficient and repeatable adsorption and desorption of water contaminations[J]. Journal of Materials Chemistry, 2012, 22(38): 20197-20202.

[22] Chen Zong-ping , Ren Wen-cai, Gao Li-bo, et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nature Materials, 2011, 10(6): 424-428.

[23] Michael Thompson Pettes, Ji Heng-xiong, Rodney S. Ruoff, et al. Thermal transport in three-dimensional foam architectures of few-layer graphene and ultrathin graphite[J]. Nano Letters, 2012, 12(6): 2959-2964.

[24] Cao Xie-hong, Shi Yu-meng, Shi Wen-hui, et al. Preparation of novel 3D graphene networks for supercapacitor applications[J]. Small, 2011, 7(22): 3163-3168.

[25] Zhou Mi, Lin Tian-quan, Huang Fu-qiang, et al. Highly conductive porous graphene/ceramic composites for heat transfer and thermal energy storage[J]. Advanced Functional Materials, 2013, 23(18): 2263–2269.

[26] Ning Guo-qing, Fan Zhuang-jun, Wang Gang, et al. Gram-scale synthesis of nanomesh graphene with high surface area and its application in supercapacitor electrodes[J]. Chemical Communications, 2011, 47(21): 5976-5978.

[27] Matthias Mecklenburg, Arnim Schuchardt, Yogendra KumarMishra, et al. Aerographite: ultra lightweight, flexible nanowall, carbon microtube material with outstanding mechanical performance[J]. Advanced Materials, 2012, 24(26): 3486-3490.

[28] Lee Jung-soo, Ahn Hvo-jin, Yoon Jong-chul. Three-dimensional nano-foam of few-layer graphene grown by CVD for DSSC[J]. Physical Chemistry Chemical Physics, 2012, 14(22): 7938-7943.

[29] Li Wei-wei, Gao Song, Wu Li-qiong, et al. High-density three-dimension graphene macroscopic objects for high-capacity removal of heavy metal ions[J]. Scientific Reports, 2013, 3(7): 120-120.

[30] Chen Ceng-meng, Zhang Qiang, Huang Chun-Hsien, et al. Macroporous ‘bubble’ graphene film via template-directed ordered-assembly for high rate supercapacitors[J]. Chemical Communications, 2012, 48(57):7149-51.

[31] Choi Bong-gill, Yang Minho, Hong Won-hi, et al. 3D macroporous graphene frameworks for supercapacitors with high energy and power densities[J]. Acs Nano, 2012, 6(5): 4020-4028.

[32] Huang Xiao-dan, Qian Kun, Yang Jie, et al. Functional nanoporous graphene foams with controlled pore sizes[J]. Advanced Materials, 2012, 24(32): 4419-4423.

[33] Luis Estevez, Antonios Kelarakis, Qian-ming Gong, et al. Multifunctional graphene/platinum/nafion hybrids via ice templating[J]. Journal of the American Chemical Society, 2011, 133 (16): 6122-6125.

[34] Yu Gui-hua, Hu Liang-bing, Michael Vosgueritchian, et al. Solution-processed graphene/MnO2 nanostructured textiles for high-performance electrochemical capacitors[J]. Nano Letters, 2011, 11(7): 2905-2911.

[35] Dong Xiao-chen, Xu Hang, Wang Xue-wan W, et al. 3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J]. Acs Nano, 2012, 6(4): 3206-3213.

[36] Yu Xin-zhi, Lu Bing-an, XuZhi. Super long-life supercapacitors based on the construction of nanohoneycomb-like strongly coupled CoMoO4-3D graphene hybrid electrodes[J]. Advanced Materials, 2014, 26(7): 1044-1051.

[37] Umakant Patil, Lee Su-chan, J. S. Sohn , et al. Enhanced symmetric supercapacitive performance of Co(OH) 2 nanorods decorated conducting porous graphene foam electrodes[J]. Electrochimica Acta, 2014, 129(16): 334-342.

[38] Jun Seong-chan, Umakant Patil, Sohn Ji-soo, et al. Enhanced supercapacitive performance of chemically grown cobalt-nickel hydroxides on three-dimensional graphene foam electrodes[J]. Acs Applied Materials & Interfaces, 2014, 6(4): 2450-2458.

[39] Chen Sheng, Zhun Jun-wu, Qiu Ling, et al. Facile fabrication of nanoparticles confined in graphene films and their electrochemical properties[J]. Chemistry (Weinheim an der Bergstrasse, Germany), 2013, 19(23): 7631–7636.

[40] Yan Lin, Li Rui-yi, Li Zai-jun, et al. Three-dimensional activated reduced graphene oxide nanocup/nickel aluminum layered double hydroxides composite with super high electrochemical and capacitance performances[J]. Electrochimica Acta, 2013, 95(11): 146–154.

[41] Wu Zhong-Shuai, Sun Yi, Yan Zhi-yuan, et al. Three-dimensional graphene-based macro- and mesoporous frameworks for high-performance electrochemical capacitive energy storage [J]. Journal of the American Chemical Society, 2012, 134(48): 19532-19535.

[42] Zhu Xiao-li, Zhang Peng, Xu Shuan, et al. Free-standing three-dimensional graphene/manganese oxide hybrids as binder-free electrode materials for energy storage applications[J]. Acs Applied Materials & Interfaces, 2014, 6(14): 11665-11674.

[43] Wang Huan-wen, Xu Zi-jie, Yi Huan, et al. One-step preparation of single-crystalline Fe2O3 particles/graphene composite hydrogels as high performance anode materials for supercapacitors[J]. Nano Energy, 2014, 7(7): 86-96.

[44] Luan Van-Hoang, Chung Jin-suk, Hur Seung-hyun. Preparation of a reduced graphene oxide hydrogel by Ni ions and its use in a supercapacitor electrode[J]. Rsc Advances, 2015, 5: 22753-22758.

[45] Xu Yu-xi, Huang Xiao-qing, Lin Zhao-yang , et al. One-step strategy to graphene/Ni(OH)2 composite hy-drogels as advanced three-dimensional supercapacitor electrode materials[J]. Nano Research, 2012, 6(1): 65-76.

[46] Liu Miao-miao, Sun Jing. In situ growth of monodisperse Fe3O4 nanoparticles on graphene as flexible paper for supercapacitor[J]. J.mater.chem.a, 2014, 2(30): 12068-12074.

[47] Niu Zhi-qiang, Liu Li-li, Zhang Li, et al. A universal strategy to prepare functional porous graphene hybrid architectures[J]. Advanced Materials, 2014, 26(22): 3681-3687.

[48] Lee Minoh, Suresh Kannan Balasingam, Jeong Hu-yong, et al. One-step hydrothermal synthesis of graphene decorated V2O5 nanobelts for enhanced electrochemical energy storage[J]. Scientific Reports, 2015, 5.

[49] He Yong-min, Chen Wan-jun, Li Xiao-dong, et al. Freestanding three-dimensional graphene/MnO2 composite networks as ultralight and flexible supercapacitor electrodes[J]. Acs Nano, 2012, 7(1):174-182.

[50] Li Chen, Zhang Xiong, Wang Kai, et al. Three dimensional graphene networks for supercapacitor electrode materials[J]. Xinxing Tan Cailiao/new Carbon Materials, 2015, 93(3):193-206.

[51] 周国珺, 叶志凯, 石微微, 等. 三维(3D)石墨烯及其复合材料的应用[J]. 化学进展, 2014(6): 950-960.

[52] 张丽芳, 魏伟, 吕伟, 等. 石墨烯基宏观体:制备、性质及潜在应用[J]. 新型炭材料, 2013, 28(3):161-171.

[53] Jiang Hao, Lee Pooi See, Li Chun chun-zhong. 3D carbon based nanostructures for advanced supercapacitors[J]. Energy & Environmental Science, 2012, 6(1): 41-53.

Privacy Policy | Copyright © 2011-2024 Ivy Publisher. All Rights Reserved.

Contact: customer@ivypub.org